Researchers have developed a new photo-uncaging system for photodynamic cancer therapy using organorhodium(III) phthalocyanine complexes that are activated in situ by pulsed light to release alkyl ...
Oxidation of saturated C−H bonds is a key chemical reaction in synthetic chemistry and chemical industry. Nevertheless, the high bond dissociation energies (BDEs) and weak polarity of C(sp 3)−H bonds, ...
Because ketones are widespread in organic molecules, chemists are eager to develop new reactions that use them to form chemical bonds. One challenging reaction is the one-electron reduction of ketones ...
It is a truth universally acknowledged in chemical synthesis that a molecule in posession of multiple stereocenters must be difficult to make. But the combined abilities of biochemistry and radical ...